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Biodiesel Synthesis with Iron Oxide Nano-Catalyst Catalyzed Pongamia Pinnata Seed Oil and Dimethyl Carbonate

Received: 20 October 2018     Accepted: 2 November 2018     Published: 28 November 2018
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Abstract

The aim of this research was to investigate the biodiesel production from Pongamia pinnata seed oil and dimethyl carbonate with an iron oxide nano-catalyzed transesterification reaction. A significant biodiesel yield (96%) was obtained with optimal operating conditions as the dimethyl carbonate to oil molar ratio (5:1), iron oxide nano-catalyst (50 mg% based on oil weight), agitation speed of 150 rpm and 60°C temperature for 5 h reaction time. The produced methyl esters from the transesterification process were confirmed to be almost identical to commercial standard biodiesel by thin layer chromatography. The produced methyl esters were analyzed by gas chromatography-mass spectrometry using an internal standard. Properties of methyl esters were characterized such as kinematic viscosity at 40°C, specific gravity at 25°C, flash point, cloud point, pour point, copper strip corrosion and acid value. The properties of the produced biodiesel were within the specifications of the American biodiesel standard, ASTM D6751-02. The results showed that all of tested reaction variables in this study had positive effects. In this research studied, a novel method has developed for production of biodiesel under mild conditions using DMC and iron oxide nano-catalyst. Iron oxide nano-catalyst could be potential candidate for use in the large-scale biodiesel production.

Published in American Journal of Energy Engineering (Volume 6, Issue 3)
DOI 10.11648/j.ajee.20180603.11
Page(s) 21-28
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2018. Published by Science Publishing Group

Keywords

Pongamia Pinnata Oil, Iron Oxide Nano-catalyst, Dimethyl Carbonate, TLC, GC-MS

References
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Cite This Article
  • APA Style

    Balaji Panchal, Qin Shenjun, Wang Jinxi, Bian Kai, Tao Chang. (2018). Biodiesel Synthesis with Iron Oxide Nano-Catalyst Catalyzed Pongamia Pinnata Seed Oil and Dimethyl Carbonate. American Journal of Energy Engineering, 6(3), 21-28. https://doi.org/10.11648/j.ajee.20180603.11

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    ACS Style

    Balaji Panchal; Qin Shenjun; Wang Jinxi; Bian Kai; Tao Chang. Biodiesel Synthesis with Iron Oxide Nano-Catalyst Catalyzed Pongamia Pinnata Seed Oil and Dimethyl Carbonate. Am. J. Energy Eng. 2018, 6(3), 21-28. doi: 10.11648/j.ajee.20180603.11

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    AMA Style

    Balaji Panchal, Qin Shenjun, Wang Jinxi, Bian Kai, Tao Chang. Biodiesel Synthesis with Iron Oxide Nano-Catalyst Catalyzed Pongamia Pinnata Seed Oil and Dimethyl Carbonate. Am J Energy Eng. 2018;6(3):21-28. doi: 10.11648/j.ajee.20180603.11

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  • @article{10.11648/j.ajee.20180603.11,
      author = {Balaji Panchal and Qin Shenjun and Wang Jinxi and Bian Kai and Tao Chang},
      title = {Biodiesel Synthesis with Iron Oxide Nano-Catalyst Catalyzed Pongamia Pinnata Seed Oil and Dimethyl Carbonate},
      journal = {American Journal of Energy Engineering},
      volume = {6},
      number = {3},
      pages = {21-28},
      doi = {10.11648/j.ajee.20180603.11},
      url = {https://doi.org/10.11648/j.ajee.20180603.11},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajee.20180603.11},
      abstract = {The aim of this research was to investigate the biodiesel production from Pongamia pinnata seed oil and dimethyl carbonate with an iron oxide nano-catalyzed transesterification reaction. A significant biodiesel yield (96%) was obtained with optimal operating conditions as the dimethyl carbonate to oil molar ratio (5:1), iron oxide nano-catalyst (50 mg% based on oil weight), agitation speed of 150 rpm and 60°C temperature for 5 h reaction time. The produced methyl esters from the transesterification process were confirmed to be almost identical to commercial standard biodiesel by thin layer chromatography. The produced methyl esters were analyzed by gas chromatography-mass spectrometry using an internal standard. Properties of methyl esters were characterized such as kinematic viscosity at 40°C, specific gravity at 25°C, flash point, cloud point, pour point, copper strip corrosion and acid value. The properties of the produced biodiesel were within the specifications of the American biodiesel standard, ASTM D6751-02. The results showed that all of tested reaction variables in this study had positive effects. In this research studied, a novel method has developed for production of biodiesel under mild conditions using DMC and iron oxide nano-catalyst. Iron oxide nano-catalyst could be potential candidate for use in the large-scale biodiesel production.},
     year = {2018}
    }
    

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  • TY  - JOUR
    T1  - Biodiesel Synthesis with Iron Oxide Nano-Catalyst Catalyzed Pongamia Pinnata Seed Oil and Dimethyl Carbonate
    AU  - Balaji Panchal
    AU  - Qin Shenjun
    AU  - Wang Jinxi
    AU  - Bian Kai
    AU  - Tao Chang
    Y1  - 2018/11/28
    PY  - 2018
    N1  - https://doi.org/10.11648/j.ajee.20180603.11
    DO  - 10.11648/j.ajee.20180603.11
    T2  - American Journal of Energy Engineering
    JF  - American Journal of Energy Engineering
    JO  - American Journal of Energy Engineering
    SP  - 21
    EP  - 28
    PB  - Science Publishing Group
    SN  - 2329-163X
    UR  - https://doi.org/10.11648/j.ajee.20180603.11
    AB  - The aim of this research was to investigate the biodiesel production from Pongamia pinnata seed oil and dimethyl carbonate with an iron oxide nano-catalyzed transesterification reaction. A significant biodiesel yield (96%) was obtained with optimal operating conditions as the dimethyl carbonate to oil molar ratio (5:1), iron oxide nano-catalyst (50 mg% based on oil weight), agitation speed of 150 rpm and 60°C temperature for 5 h reaction time. The produced methyl esters from the transesterification process were confirmed to be almost identical to commercial standard biodiesel by thin layer chromatography. The produced methyl esters were analyzed by gas chromatography-mass spectrometry using an internal standard. Properties of methyl esters were characterized such as kinematic viscosity at 40°C, specific gravity at 25°C, flash point, cloud point, pour point, copper strip corrosion and acid value. The properties of the produced biodiesel were within the specifications of the American biodiesel standard, ASTM D6751-02. The results showed that all of tested reaction variables in this study had positive effects. In this research studied, a novel method has developed for production of biodiesel under mild conditions using DMC and iron oxide nano-catalyst. Iron oxide nano-catalyst could be potential candidate for use in the large-scale biodiesel production.
    VL  - 6
    IS  - 3
    ER  - 

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Author Information
  • Key Laboratory for Resource Exploration Research, Hebei University of Engineering, Handan, China

  • Key Laboratory for Resource Exploration Research, Hebei University of Engineering, Handan, China

  • Key Laboratory for Resource Exploration Research, Hebei University of Engineering, Handan, China

  • Key Laboratory for Resource Exploration Research, Hebei University of Engineering, Handan, China

  • Key Laboratory for Resource Exploration Research, Hebei University of Engineering, Handan, China

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